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Beilstein J. Org. Chem. 2018, 14, 998–1003, doi:10.3762/bjoc.14.85
Graphical Abstract
Scheme 1: Pd-catalyzed aminations at C-2 or C-4 in the 13α-estrone series. Reactions were performed on a 0.25...
Scheme 2: Two-step synthesis of 2-amino-13α-estra-1,3,5(10)-trien-17-one (13).
Beilstein J. Org. Chem. 2017, 13, 1303–1309, doi:10.3762/bjoc.13.126
Scheme 1: Syntheses of 2- or 4-phenethynyl-13α-estrones (8–11) by Sonogashira coupling.
Scheme 2: Partial or full hydrogenation of compounds 8c–11c.